That really depends on the HTML structure. You can see if parameter index can help you to select an item from a list. However, this only works on the lowest level element you selected in the select definition.
ok, i couldnt find a solution for the scrape sensor, but made a little python script with pandas and request:
import pandas as pd
import requests
url = "https://dawum.de/Bundestag/"
r = requests.get(url)
df_list = pd.read_html(r.text) # this parses all the tables in webpages to a list
df = df_list[0].loc[0,2].rstrip("%")
print(df);
now I can use this script as a command_line sensor, that works fine so far: