To expand on patkap…
The command_line sensor does not implement icon_template.
So to do what you want to do, create a new template sensor like this:
- platform: template value_template: {{state.sensor.hombot_battery.state}} name: HomBot_Battery_Display unit_of_measurement: "%" icon_template: "{% if is_state('sensor.hombot_battery', '100') %}mdi:battery{% else %}mdi:battery-unknown{% endif %}"