Hi,
My router and (almost) all of my clients use dual-stack IPv4 + IPv6 EXCEPT devices using MQTT due to an issue report I filed back in 2022:
Note the GitHub issue comment (which could be out of date now):
I’ve not tested IPv6 with HASS since, although almost all of my Fedora Fedora devices talk between themselves using IPv6.
My HASS setup is a Yellow running supervised with Android devices so I might be able to help with some testing.
TTFN,
James