Temperature history in Graph

Surprised it was giving any values at all!

I think you want no colon on the name, and the degrees symbol in the unit:

template:
  sensor:
    - name: Heizung Esszimmer Temperatursensor
      state: "{{ state_attr('climate.smart_thermostat_210940168395749','current_temperature')}}"
      unit_of_measurement: "°C"
      device_class: temperature 
      state_class: measurement

…and note that you’ll only get the graph once the old unit-less measurements have “expired” from the graph window.