trigger:
- platform: state
entity_id: sensor.power_highest_peak_time_today
- platform: time
at: sensor.power_highest_peak_time_today
condition:
- condition: template
value_template: "{{ states('sensor.power_highest_peak_time_today')|as_timestamp <= now()|as_timestamp }}"
action:
...
That will trigger every time the sensor changes and its new state is now or earlier; or when the time on the sensor is reached.