CO2 Zigbee controller automation no longer starts in the morning

I am a total beginner that doesn’t speak yamI or json please advise accordingly. I apologize the error code informed me that even though I cut and pasted from the file, my back ticks are improper but I couldnt correct them. sorry
If there are more elegant ways to program I am open to suggestions beyond solving my problem

It could be the MODE both automations are set to SINGLE is that correct?

I monitor CO2 with a zigbee co2 sensor by ALAB, and control a valve with a sonoff zigbee relay switch.
It works fabulously holding to about ± 20ppm, but I have some how messed its morning startup.

Problem: the automation no longer begins at 8:01 am. I now have to start it manually, and then it works fine the rest of the day until 7:45 pm end time.

There are 2 automations that I use …

  1. CO2 750 ppm Controller Max limit and ( Turns valve OFF any time above 650ppm)
  2. CO2 750 ppm Controller 8am to 8pm Activation (supposed to turn ON valve below 648ppm with the condition that it is after 8:01 am but before 7:45 pm )
  • id: ‘1659477287617’
    alias: CO2 750 ppm Controller Max limit
    description: Holds CO2 700 to 800
    trigger:
    • platform: numeric_state
      entity_id: sensor.co2_temp_humidity_alab_co2
      for:
      hours: 0
      minutes: 0
      seconds: 0
      attribute: co2
      above: ‘650’
      condition: []
      action:
    • type: turn_off
      device_id: bfe64e0199bbb2cf6d5d792a73d573e9
      entity_id: switch.co2_relay_0x00124b00226c90e7
      domain: switch
      mode: single
  • id: ‘1659540607748’
    alias: ’ CO2 750 ppm Controller 8am to 8pm Activation ’
    description: ‘’
    trigger:
    • platform: numeric_state
      entity_id: sensor.co2_temp_humidity_alab_co2
      for:
      hours: 0
      minutes: 0
      seconds: 0
      attribute: co2
      below: ‘648’
      condition:
    • condition: time
      before: ‘19:45:00’
      after: 08:01:00
      weekday:
      • sun
      • mon
      • tue
      • wed
      • thu
      • fri
      • sat
        action:
    • type: turn_on
      device_id: bfe64e0199bbb2cf6d5d792a73d573e9
      entity_id: switch.co2_relay_0x00124b00226c90e7
      domain: switch
      mode: single