Homematic (HMIP-RFUSB): no devices found after switch to RaspberryMatic

The Connection refused errors indicate, that there is some sort of connectivity issue. Either network or firewall. I don’t know how it is with the RaspberryMatic Add-On out of the box, but I know RaspberryMatic itself has a firewall, and there you have to allow access from Home Assistant. That’s also mentioned in the Docs.