OK, so your Home Assistant has the Daikin AC in an integration, which provides the A/C unit as an entity under the climate domain, as well as a bunch of sensors.
The HA entity climate.daikinap81365 has a state, and has a bunch of attributes.
In Home Assistant, you will find that you can use a service call, using the ‘Climate’ domain, and a service ‘Turn off’. This service call requires a target entity, which will be your climate.daikinap81365.
If you test this out in HA, using Developer Tools > Services, you should be able to turn off the A/C unit.
If you cannot run this service call in HA, there is no way you can get it to work in Node-RED, so please test it in HA first.
Now, the global variable that holds homeassistant states is read only and there is no way to change these values. If you attempt to change these values, then nothing will happen as they are copied from HA to NR, but not the other way around.
To change things in HA, from Node-RED, we use service calls.
If you use the Call Service node, and set this up with domain ‘climate’ and service ‘turn_off’ and entity ‘climate.dainkinap81236’, then this should call the ‘turn off’ service and turn off your A/C unit.
Since ‘turn off’ does nothing complicated, there is no Data field required.