You can only use value_json in the rest sensor.
You need to use the same format as your status sensor. Meaning:
cmi34_tkollektor:
value_template: '{{ states.sensor.cmi34.attributes["Data"]["Inputs"][0]["Value"]["Value"] }}'
friendly_name: 'TKollektor'
Or better:
cmi34_tkollektor:
value_template: '{{ states_attr('sensor.cmi34','Data')["Inputs"][0]["Value"]["Value"] }}'
friendly_name: 'TKollektor'
Since it won’t display errors at startup.