Verisure alarm as trigger for automation (need help)

Take a look at the documentation for conditions. This bit is wrong. You need to have multiple conditions.

condition:
    condition: or  # 'when dark' condition: either after sunset or before sunrise
    conditions:
      - condition: sun
        after: sunset
      - condition: sun
        before: sunrise

Check out the documentation:

Sunset to Sunrise will not work because it crosses the reset. Days reset at midnight. So anything after sunset does not equal before sunrise. You want to write your condition based on before sunrise OR after sunset.

before sunrise = 0 to sunrise. after sunset = sunset to 24 (or midnight).